After you’ve completed your deployment of Exchange 2016, and test connectivity via Exchange Remote Connectivity tool, you can move mailboxes to your Exchange 2016 Mailbox server.
Migrate Mailboxes
Configuring the Default Mailbox Database for Exchange Server 2016
Logon Exchange 2016 Server, open Exchange Management Shell.
Get all mailbox databases information via follow cmdlet.
Get-MailboxDatabase -IncludePreExchange2013
3. Change the Default Mailbox Database name via follow cmdlet.
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